Dehydration/amine intercalation in Zn(O3PR)-H2O phosphonates: the missing link, X-ray structure of Zn(O3PCH3)

Authors
Bujoli-Doeuff, M Evain, M Jaffres, PA Caignaert, V Bujoli, B
Citation
M. Bujoli-doeuff et al., Dehydration/amine intercalation in Zn(O3PR)-H2O phosphonates: the missing link, X-ray structure of Zn(O3PCH3), INT J INORG, 2(6), 2000, pp. 557-560
Citations number
19
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS
ISSN journal
14666049 → ACNP
Volume
2
Issue
6
Year of publication
2000
Pages
557 - 560
Database
ISI
SICI code
1466-6049(200012)2:6<557:DIIZPT>2.0.ZU;2-L
Abstract
The hydrothermal synthesis of colorless crystals of Zn(O3PCH3) was achieved using a solution of zinc nitrate and methylphosphonic acid (1:1) in water, in the presence of thiourea. The structure was determined by single crysta l X-ray diffraction [monoclinic, space group P2(1)/c (No. 14), a=8.7226(9) Angstrom, b=5.2156(7) Angstrom, c=10.847(1) Angstrom, V=389.48(9) Angstrom (3), Z=2]. From this result, the mechanism of the structure modification ta king place during the dehydration of Zn(O3PR)-H2O phosphonates was clearly demonstrated. (C) 2000 Elsevier Science Ltd. All rights reserved.