The partial substitution of manganese for vanadium in the perovskite-l
ike sheets of Bi4V2O11 has allowed to stabilize at room temperature th
e structure of gamma-Bi4V2O11 for 0.15 less than or equal to x less th
an or equal to 0.50. Magnetic measurements have shown that the mangane
se offers simultaneously the +III and +IV oxidation states. It results
that the materials prepared can be formulated: Bi4V2-xMx-y3+Mny4+O11-
x+y/2 (delta=x-y/2). Study of electrical properties has revealed the p
resence of a mixed contribution, at the same time electronic and ionic
, in these materials. The conductivity of the (x=0.20) composition is
mainly ionic and its value locates this material among the best ionic
conductors or gamma-Bi4V2O11 structural type. (C) 1997 Elsevier Scienc
e S.A.