Citation
M. Westerhausen et al., Homoleptic triisopropylsilylarsandiides of magnesium and divalent tin, J ORGMET CH, 614, 2000, pp. 70-73
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X
→ ACNP
Volume
614
Year of publication
2000
Pages
70 - 73
Database
ISI
SICI code
0022-328X(200012)614:<70:HTOMAD>2.0.ZU;2-N
Abstract
The magnesiation of H2AsSi'Pr-3 yields the tetramer [(THF)MgAsSi'Pr-3](4) (
1) with a central Mg4As4 heterocubane moiety. The reaction of Sn[N(SiMe3)(2
)](2) with triisopropylsilylarsane gives the hexamer [(SnAsSiPr3)-Pr-i](6)
(2) with an inner hexagonal Sn,As, prism. The molecular structures of both
these compounds have been determined. (C) 2000 Elsevier Science B.V. All ri
ghts reserved.