Citation
Ce. Housecroft et al., Boride cluster fusion through copper and silver. Crystal structure of [(Ph3P)(2)N][(HRu4(CO)(12)BH)(2)Ag], J ORGMET CH, 614, 2000, pp. 202-207
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X
→ ACNP
Volume
614
Year of publication
2000
Pages
202 - 207
Database
ISI
SICI code
0022-328X(200012)614:<202:BCFTCA>2.0.ZU;2-B
Abstract
Reaction of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Cu(NCMe)(4)][BF4] in the pre
sence of [(Ph3P)(2)N]Cl leads to [(Ph3P)(2)N][HRu4(CO)(12)B)(2)Cu-4(mu -Cl)
]Cl, confirmed by a single crystal structure determination. A silver analog
ue is produced from the reactions of [(Ph3P)(2)N][HRu4(CO)(12)BH] with [Ag(
NCMe)(4)][BF4] or AgBF4, but its formation competes with that of [(Ph3P)(2)
N][HRu4(CO)(12)BH)(2)Ag], the crystal structure of which has been determine
d. (C) 2000 Elsevier Science B.V. All rights reserved.