Polycarbon linked metal cluster compounds

Authors
Norton, DM Shriver, DF
Citation
Dm. Norton et Df. Shriver, Polycarbon linked metal cluster compounds, J ORGMET CH, 614, 2000, pp. 318-321
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
614
Year of publication
2000
Pages
318 - 321
Database
ISI
SICI code
0022-328X(200012)614:<318:PLMCC>2.0.ZU;2-4
Abstract
The reactions between metal cluster anions and metal cluster cations contai ning carbide ligands were explored. In one case, a salt formed which consis ted of a cluster cation along with a cluster anion. By contrast, the intera ction of [Rh2Cl2(CO)(4)] with [Fe-3(CO)(9)C2Fe(CO)(4)](2-) produced a new m onocarbide metal cluster, [Fe3Rh3(CO)(5)C](-). (C) 2000 Elsevier Science B. V. All rights reserved.