THE CRYSTAL-STRUCTURE OF SR6CU3N5 WITH ISOLATED, BENT (CU-2(I)N-3)(7-) AND THE SINGLE-CRYSTAL STRUCTURAL DETERMINATION OF SRCUN

Authors
DISALVO FJ TRAIL SS YAMANE H BRESE NE
Citation
Fj. Disalvo et al., THE CRYSTAL-STRUCTURE OF SR6CU3N5 WITH ISOLATED, BENT (CU-2(I)N-3)(7-) AND THE SINGLE-CRYSTAL STRUCTURAL DETERMINATION OF SRCUN, Journal of alloys and compounds, 255(1-2), 1997, pp. 122-129
Citations number
43
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
255
Issue
1-2
Year of publication
1997
Pages
122 - 129
Database
ISI
SICI code
0925-8388(1997)255:1-2<122:TCOSWI>2.0.ZU;2-W
Abstract
Single crystals of the ternary nitrides Sr6Cu3N5 and SrCuN were prepar ed in high pressure autoclaves at 800 degrees C. Tetragonal crystals o f the nitridocuprate, Sr6Cu3N5 crystallized in space group P4(2)mc (no . 105), a=8.649(1) Angstrom, c=7.325(1) Angstrom. This compound repres ents a new structure type characterized by a mixture of linear ((CuN2) -N-I)(5-) and unprecedented V-shaped ((Cu2N3)-N-I)(7-) nitridometallat e anions. The crystal structure of SrCuN was confirmed by single cryst al data to adopt the BaNiN structure type (Pnma (no. 62), a=9.045(2), b=13,234(3), c=5.388(1) Angstrom; Z=12).