Sensory green attribute intensities, the total amount of complex phenolic c
ompounds and the composition of volatile compounds from lipoxygenase pathwa
ys were measured in oils obtained from both industrial centrifugation plant
s and different kinds of laboratory mill. These data were evaluated by hier
archical cluster analysis, principal component analysis and linear discrimi
nant analysis with the aim of distinguishing oil samples in relation to the
extraction methodology. The statistical tests showed that the mentioned va
riables were able to differentiate oils according to the method adopted for
their extraction from olive pastes. Oils from laboratory mills were clearl
y different from samples extracted industrially. This implies that results
derived from investigations carried out using oils obtained from laboratory
mills cannot be immediately transferred to oils from industrial plants. Oi
ls from dual-phase decanters in industrial plants were more similar to samp
les extracted in conventional tri-phase industrial plants, even if they wer
e all well differentiated according to the oil extraction methodology. (C)
2000 Society of Chemical Industry.