Photoemission evidence of electronic stabilization of polar surfaces in K3C60

We present a detailed investigation of the surface electronic structure of solid K3C60 in connection with its electronic transport properties. We find that the conductivity is extremely sensitive to the K concentration of the surface layer, and that the best-conducting samples with the highest super conducting transition temperatures have surfaces with the highest density o f states at the Fermi level as measured by photoemission. The C-60 ions at the surface have, however, a valence that deviates appreciably from the 3- bulk value, namely 2.5- or even 1.5-, depending on the preparation procedur e. We attribute this as being the result of an electronic rather than an at omic surface reconstruction to avoid the divergence of the electrostatic po tential associated with the polar (111) surface termination of K3C60. We ar gue that such a mixed-valence surface should always be a metal, irrespectiv e of whether the bulk is a metal or a Mott-Hubbard insulator.