P. Garcia-gonzalez et al., Image potential and the exchange-correlation weighted density approximation functional, PHYS REV B, 62(23), 2000, pp. 16063-16068
It is known that the exchange-correlation (XC) potential nu (XC) obtained b
y using the weighted density approximation (WDA) does not yield the correct
image behavior - 1/4z outside a metal surface. Some authors have speculate
d that this limitation could be overcome by symmetrizing the XC hole, using
a two-point scaling factor in its modelization by the WDA. In this work, w
e show that this symmetrization procedure does not improve the XC potential
nu (XC), and makes it unphysical. Alternatively, we present a WDA scheme b
ased on an anisotropic scaling for the XC hole, constructed to verify both
the normalization of the XC hole and the exact value of the second momenta
of the XC hole. In this last case, the potential nu (XC) has the correct im
age decay.