The time evolution of changes in the optical absorption coefficient with il
lumination has been studied for a-As2S3 films at 50, 100, 200, and 300 K in
order to characterize the dynamics of photodarkening. The magnitude of the
changes is larger at the lower temperatures. A model of photon-assisted si
te switching is proposed for the Variation of photodarkening with time, in
which the fractional growth in the concentration of photodarkened sites is
expressed by a stretched exponential function.