P. Haas et al., Correlation gap in the optical spectra of the two-dimensional organic metal (BEDT-TTF)(4)[Ni(dto)(2)], PHYS REV B, 62(22), 2000, pp. R14673-R14676
Optical reflection measurements within the highly conducting (a,b) plane of
the organic metal (BEDT-TTF)(4)[Ni(dto)(2)] reveal the gradual development
of a sharp feature at around 200 cm(-1) as the temperature is reduced belo
w 150 K. Below this frequency a narrow Drude-like response is observed whic
h accounts for the metallic behavior. Since de Haas-van Alphen oscillations
at low temperatures confirm band structure calculations of bands crossing
the Fermi energy, we assign the observed behavior to a two-dimensional meta
llic state in the proximity of a correlation induced metal-insulator transi
tion.