Systematic properties of the first excited state are presented for various
ring sizes and spin quantum numbers which are only partly covered by the th
eorem of Lieb, Schultz, and Mattis. For odd ring sizes the first excited en
ergy eigenvalue shows unexpected degeneracy and related shift quantum numbe
rs. As a byproduct the ground state energy as well as the energy of the fir
st excited state of infinite chains are calculated by extrapolating the pro
perties or only a few, finite, antiferromagnetically coupled Heisenberg rin
gs using the powerful Levin sequence acceleration method.