Yq. Ma, Wetting-driven structure formation of a binary mixture in the presence of a mobile particle pinning potential, PHYS REV E, 62(6), 2000, pp. 8207-8211
We investigate the pattern formation on the solid substrate of phase-separa
ting films containing mobile wetting particles with a preferential attracti
on for one component of the mixtures. The presence of mobile particles unde
r the surface-particle interaction modulation breaks the isotropy of the bu
lk phase-separating process, leading to the formation of orientational stru
cture due to the interplay between phase separation and wetting particle or
dering under a modulated pinning potential at the late stage. Simulations s
uggest that the phase-separation morphology can be changed through the adju
stment of the wettable-phase-particle interaction and the surface-particle
interaction. It provides some important insights into this "wetting-directe
d spinodal decomposition.".