Structural characteristics and gas permeation properties of polynorbornenes with retained bicyclic structure

Polynorbornenes of different molecular weights were synthesised by addition polymerisation, using a nickel based catalyst. This polymerisation route l eads to amorphous polymers that were shown to display unique properties: hi gh glass transition temperature, rigid random coil conformation, and dense packing in the amorphous state. Gas permeation membranes were prepared from these addition type nonsubstituted polynorbornenes. A study of their gas t ransport properties was performed and compared with both substituted additi on polynorbornenes and ring opening metathesis polymerised polynorbornenes. The observed behaviour, in terms of permeability and selectivity, is in ac cordance with the low free volume and the dense packing confirmed by positr on annihilation spectroscopy and WAXD in these polymer structures. (C) 2000 Elsevier Science Ltd. All rights reserved.