G. Malucelli et al., Water sorption in polymer network films synthesised from PEO oligomers containing acrylic and vinyl ether functionalities, POLYM BULL, 45(4-5), 2000, pp. 431-438
Poly(ethylene oxide) oligomers, with end groups that have either acrylic or
vinyl ether functionalities, were photopolymerised by UV radiation to crea
te polymer networks in the form of thin films. Moisture sorption of the pol
ymers, determined by microgravimetric analysis, was correlated to the oligo
mer structure, i.e. to the PEO chain length and to the type of unsaturation
. The data can be described with a Fickian diffusion model using diffusion
coefficients of water in the polymer networks on the order of 1 x 10(-12) m
(2)/s. The total amount of water sorption at equilibrium saturation increas
es with an increasing number of EO units in the oligomer used to synthesise
the network.
The number of absorbed water molecules associated with each EO unit increas
es with the number of these units in the oligomer until it reaches two wate
r molecules per EO unit, for acrylated-PEO oligomers (PEGDA) having at leas
t 30 EO units. The type of interactions between the polymer network and wat
er were evaluated by means of thermal analysis performed on the hydrated fi
lms. It was found that all water is present as bound rather than mobile wat
er.