This paper reports a surface and interface study of indium antimonide
epitaxially grown on gallium arsenide using metalorganic magnetron spu
ttering technique. X-ray photoelectron spectroscopy analysis shows tha
t the original surface of InSb is composed of InSb, In2O3, and Sb2O3,
and the binding energy of Sb 3d(5/2) decreases when an antimony atom i
s surrounded by more indium atoms. The interdiffusion phenomenon is st
udied by both Anger electron spectroscopy depth profiling and Rutherfo
rd backscattering spectroscopy, the results of which are in good agree
ment. The width of the interdiffusion region is around 900 +/- 100 Ang
strom, and independent of epilayer thickness. X-ray diffraction study
indicates that the crystallinity of the InSb epilayer becomes better w
ith the increase of epilayer thickness. It is also demonstrated that t
he crystal orientation relationship between the InSb epilayer and GaAs
substrate is (100) InSb//(100) GaAs, and the (100) crystal planes of
InSb and GaAs are parallel to the macro-surface of the InSb/GaAs heter
ostructure. (C) 1997 Elsevier Science S.A.