Electrosynthesis of triorganylphosphines from organic halides and chlorophosphines, catalyzed by nickel complexes

Authors
Budnikova, YG Kargin, YM Sinyashin, OG
Citation
Yg. Budnikova et al., Electrosynthesis of triorganylphosphines from organic halides and chlorophosphines, catalyzed by nickel complexes, RUSS J G CH, 70(4), 2000, pp. 524-528
Citations number
7
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
4
Year of publication
2000
Pages
524 - 528
Database
ISI
SICI code
1070-3632(200004)70:4<524:EOTFOH>2.0.ZU;2-1
Abstract
The possibility of cross coupling of organic halides and chlorophosphines u nder the action of electrochemically generated Ni(0) complexes of 2,2'-bipy is shown. The final triorganylphosphines are formed by several pathways, i ncluding reaction of the sigma complex of ArNiX with chlorophosphine and el ectron transfer-induced reductive elimination of Ph2PArNiX, leading to the cross-coupling product.