Structure and intramolecular mobility of N-(phosphoryl)- or N-(thiophosphoryl)amides and -thioamides: VIII. Structure of N-(thiophosphoryl)-S-organylbenzimidothioates by NMR spectroscopy

Authors
Karataeva, FK Sokolov, FD Zabirov, NG
Citation
Fk. Karataeva et al., Structure and intramolecular mobility of N-(phosphoryl)- or N-(thiophosphoryl)amides and -thioamides: VIII. Structure of N-(thiophosphoryl)-S-organylbenzimidothioates by NMR spectroscopy, RUSS J G CH, 70(4), 2000, pp. 529-532
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
4
Year of publication
2000
Pages
529 - 532
Database
ISI
SICI code
1070-3632(200004)70:4<529:SAIMON>2.0.ZU;2-X
Abstract
N-(Diisopropoxythiophosphoryl)- and N-(diisopropoxyphosphoryl)-S-organylben zimidothioates, which contain one and two imidothiol fragments, are structu rally homogeneous in solutions. Cis arrangement of the Ph and P(X)(OPr-i)(2 ) substituents about the C=N bond (E isomer) was deduced from the (3)J(PNCC ) constants.