DIASTEREOSELECTIVE INTRAMOLECULAR DIELS-ALDER REACTIONS TOWARDS THE SYNTHESIS OF A TAXOL C-RING PRECURSOR

Citation
L. Grimaud et al., DIASTEREOSELECTIVE INTRAMOLECULAR DIELS-ALDER REACTIONS TOWARDS THE SYNTHESIS OF A TAXOL C-RING PRECURSOR, Tetrahedron, 53(27), 1997, pp. 9253-9268
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
53
Issue
27
Year of publication
1997
Pages
9253 - 9268
Database
ISI
SICI code
0040-4020(1997)53:27<9253:DIDRTT>2.0.ZU;2-P
Abstract
Intramolecular Diels-Alder reactions have been used for the synthesis of cishydroisobenzofuranones 23 or 21, which represents a potential pr ecursor of taxol C-ring. Easy preparation of beta-ketoesters 7a and 7b is also described. (C) 1997 Elsevier Science Ltd.