ENANTIOSELECTIVE SYNTHESIS OF 6 MEMBERED CARBOCYCLES THROUGH [4-AMINO-1,3-BUTADIENES AND TUNGSTEN VINYL FISCHER-TYPE CARBENE COMPLEXES(2]CYCLOADDITION REACTIONS OF CHIRAL 2)

Authors
BARLUENGA J AZNAR F MARTIN A BARLUENGA S
Citation
J. Barluenga et al., ENANTIOSELECTIVE SYNTHESIS OF 6 MEMBERED CARBOCYCLES THROUGH [4-AMINO-1,3-BUTADIENES AND TUNGSTEN VINYL FISCHER-TYPE CARBENE COMPLEXES(2]CYCLOADDITION REACTIONS OF CHIRAL 2), Tetrahedron, 53(27), 1997, pp. 9323-9340
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
27
Year of publication
1997
Pages
9323 - 9340
Database
ISI
SICI code
0040-4020(1997)53:27<9323:ESO6MC>2.0.ZU;2-1
Abstract
2-Amino-1,3-butadienes 1 react with carbene complexes 2 to yield, afte r hydrolysis, cyclohexanone derivatives. The use of chiral enantiomeri cally pure dienes 19 allow the access to enantio-enriched cycloadduct complexes. (C) 1997 Elsevier Science Ltd.