In order to improve the properties of transparent conductive thin films we
have developed a range of multilayer coatings consisting of three to five a
lternating layers of metals and high refractive index dielectrics. We have
used physical vapor deposition (electron gun and thermal evaporation) to pr
epare optimized coatings with excellent optical and electrical properties,
improved thermal endurance and long-term stability. They compare favorably
with equivalent doped metal oxide films. We have used ZnS/Ag/ZnS films succ
essfully as electrodes in electrochromic devices prepared in our laboratory
. These coatings suppress emissive heat losses and prevent overheating by s
olar IR radiation, thus improving the performance of electrochromic windows
. They can also be used as low emittance coatings in double glazings, espec
ially for solar control applications. (C) 2000 Elsevier Science B.V. All ri
ghts reserved.