A novel synthesis of functionalised tertiary phosphines by palladium catalysed phosphination with triarylphosphines

Citation
Fy. Kwong et al., A novel synthesis of functionalised tertiary phosphines by palladium catalysed phosphination with triarylphosphines, TETRAHEDR L, 41(52), 2000, pp. 10285-10289
Citations number
31
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
52
Year of publication
2000
Pages
10285 - 10289
Database
ISI
SICI code
0040-4039(200012)41:52<10285:ANSOFT>2.0.ZU;2-4
Abstract
The palladium catalysed Pd-aryl/P-aryl exchange was applied in the synthesi s of various functionalised phosphines from their corresponding substituted aryl triflates using triarylphosphines as the phosphinating agents. This m ethod tolerated many functional groups including ketone, aldehyde, ester, n itrile, methyl ether, pyridyl and chloride groups. (C) 2000 Elsevier Scienc e Ltd. All rights reserved.