Mn(OAc)(3) - an efficient oxidant for regeneration of DDQ: deprotection ofp-methoxy benzyl ethers

Authors
Sharma, GVM Lavanya, B Mahalingam, AK Krishna, PR
Citation
Gvm. Sharma et al., Mn(OAc)(3) - an efficient oxidant for regeneration of DDQ: deprotection ofp-methoxy benzyl ethers, TETRAHEDR L, 41(52), 2000, pp. 10323-10326
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
52
Year of publication
2000
Pages
10323 - 10326
Database
ISI
SICI code
0040-4039(200012)41:52<10323:M-AEOF>2.0.ZU;2-G
Abstract
Mn(OAc)(3) has been successfully developed as a new oxidant for the regener ation of DDQ from HDDQ. This DDQ regeneration technique, making use of 3 eq uiv. of Mn(OAc)(3)-DDQ (10 mol%), was applied to the deprotection of p-meth oxy benzyl (PMB) ethers. (C) 2000 Elsevier Science Ltd. All rights reserved .