On the lithium chloromolybdate Li[Mo6Cl13]

Authors
Strobele, M Meyer, HJ
Citation
M. Strobele et Hj. Meyer, On the lithium chloromolybdate Li[Mo6Cl13], Z ANORG A C, 626(12), 2000, pp. 2432-2434
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
12
Year of publication
2000
Pages
2432 - 2434
Database
ISI
SICI code
0044-2313(200012)626:12<2432:OTLCL>2.0.ZU;2-C
Abstract
Li[Mo6Cl13] was obtained as single phase product from a solid state reactio n of MoCl5, Mo powder, and LiCl at 800 degreesC. The structure as refined b y single crystal X-ray diffraction, contains one-dimensional [(Mo6Cl8Cl4Cl2 /2a-a)-Cl-i-Cl-a](-) chains, formed by Cla-a bridges. Lithium ions are loca ted in tunnels among the chain-direction, each of them being surrounded by a distorted tetrahedral arrangement of outer chlorine ligands (Cl-a) belong ing to four different clusters.