mu-Phthalocyaninato-bis({triphenylphosphine oxide}sodium): Synthesis and crystal structure

Authors
Hoberg, C Goldner, M Cornelissen, U Homborg, H
Citation
C. Hoberg et al., mu-Phthalocyaninato-bis({triphenylphosphine oxide}sodium): Synthesis and crystal structure, Z ANORG A C, 626(12), 2000, pp. 2435-2437
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
12
Year of publication
2000
Pages
2435 - 2437
Database
ISI
SICI code
0044-2313(200012)626:12<2435:MOSAC>2.0.ZU;2-M
Abstract
Blue mu -phthalocyaninato-bis({triphenylphosphine oxide)sodium) (1) is prep ared by heating triphenylphosphine oxide with disodium phthalocyaninate at 160 degreesC. 1 is centrosymmetric (space group P (1over bar>) over bar). T he Na atom is located in a tetragonal pyramid co-ordinating four isoindole N atoms at a distance varying between 2.409(2) and 2.438(2) Angstrom, and o ne O atom at 2.198(2) Angstrom. The Na-Na distance is 2.823(5) Angstrom, an d the Na-O-P angle is 145.5(1)degrees.