Citation
Pam. Williams et al., Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands, Z ANORG A C, 626(12), 2000, pp. 2509-2514
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313
→ ACNP
Volume
626
Issue
12
Year of publication
2000
Pages
2509 - 2514
Database
ISI
SICI code
0044-2313(200012)626:12<2509:COTNCC>2.0.ZU;2-1
Abstract
The crystal structure of the complexes [Cu(sac)(2)- (bzim)(2)(H2O)] (1) and
[Cu(sac)(2)(bzim)(H2O)(EtOH)]. 2 EtOH (2) (sac = saccharinate anion; bzim
= benzimidazole; EtOH=ethanol) was determined by single crystal X-ray diffr
actometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z
= 8 whereas complex 2 belongs to the triclinic P (1) over bar space group
with Z = 2, Room temperature magnetic susceptibilities as well as electroni
c and IR spectra of both complexes were discussed. Their thermal behaviour
was investigated by means of TG and DTA methods.