CO oxidation over Au/MeOx at ambient temperature and humidity

Citation
Gy. Wang et al., CO oxidation over Au/MeOx at ambient temperature and humidity, ACT CHIM S, 58(12), 2000, pp. 1557-1562
Citations number
12
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
58
Issue
12
Year of publication
2000
Pages
1557 - 1562
Database
ISI
SICI code
0567-7351(2000)58:12<1557:COOAAA>2.0.ZU;2-0
Abstract
Au/MeOx (Me = Al, Co, Cr, Cu, Fe, Mn, Ni, Zn) catalysts were prepared by a co precipitation method,and their catalytic performance for CO oxidation at ambient temperature and humidity was investigated. It was found that the a ctivity and stability of Au/MeOx were strongly dependent on the type of met al oxide support. Among the samples tested, the Au - based catalysts suppor ted on the oxides of Zn, Fe, Co, Ni and Al showed high activity, i. e. they can oxidize CO to CO2 completely at the given reaction condition. It was a lso found that these catalysts had excellent stability, the stability seque nce was Au/ZnO > Au/alpha - Fe2O3 > Au/Co3O4 > Au/gamma - Al2O3 approximate to Au/NiO. The effect of water vapor on the activity and stability were al so studied, and a positive effect for Au/ZnO and negative effects for Au/Mn Ox were observed.