Effect of the activation procedure on the performance of Mo/H-MFI catalysts for the non-oxidative conversion of methane to aromatics

The effect of pre-treatment on the performance of Mo/H-MFI zeolite catalyst s applied to the non-oxidative conversion of methane to aromatics has been investigated. It is demonstrated that catalyst performance depends on activ ation conditions. Activation of the Mo-oxide/H-MFI precursor with an n-buta ne/hydrogen mixture results in higher catalyst stability and benzene select ivity which are tentatively attributed to the formation of the alpha -MoC1- x carbide, with f.c.c. structure as revealed by XRD. (C) 2000 Published by Elsevier Science B.V.