Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system

Authors
Feuerstein, M Laurenti, D Doucet, H Santelli, M
Citation
M. Feuerstein et al., Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system, CHEM COMMUN, (01), 2001, pp. 43-44
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
01
Year of publication
2001
Pages
43 - 44
Database
ISI
SICI code
1359-7345(2001):01<43:DAOTCP>2.0.ZU;2-C
Abstract
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)-cyclopentane/[PdC l(C3H5)](2) system catalyses allylic amination in good yields with a very h igh substrate/catalyst ratio; a turnover number of 680 000 and a turnover f requency of 8125 h(-1) can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.