Aluminium-containing ring systems and N-heterocycle formation via nitrile insertions into Al-N bonds

Authors
Gibson, VC Redshaw, C White, AJP Williams, DJ
Citation
Vc. Gibson et al., Aluminium-containing ring systems and N-heterocycle formation via nitrile insertions into Al-N bonds, CHEM COMMUN, (01), 2001, pp. 79-80
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
01
Year of publication
2001
Pages
79 - 80
Database
ISI
SICI code
1359-7345(2001):01<79:ARSANF>2.0.ZU;2-L
Abstract
Reactions of Me3Al with 1,2-diaminobenzene [1,2- (H2N)(2)C6H4] or anthranil ic acid, [1,2-(H2N)(HO2- C)C6H4], followed by treatment with acetonitrile, afford tetranuclear and hexanuclear aluminium-containing ring systems; a si ngle crystal X-ray structure on the hexametallic product reveals the constr uction of quinazoline ligands arising via insertion of acetonitrile into Al -N bonds.