Solvothermal synthesis of [Cr-10(mu-O2CMe)(10)(mu-OR)(20)] 'chromic wheels' with antiferromagnetic (R = Et) and ferromagnetic (R = Me) Cr(III)center dot center dot center dot Cr(III) interactions

Authors
McInnes, EJL Anson, C Powell, AK Thomson, AJ Poussereau, S Sessoli, R
Citation
Ejl. Mcinnes et al., Solvothermal synthesis of [Cr-10(mu-O2CMe)(10)(mu-OR)(20)] 'chromic wheels' with antiferromagnetic (R = Et) and ferromagnetic (R = Me) Cr(III)center dot center dot center dot Cr(III) interactions, CHEM COMMUN, (01), 2001, pp. 89-90
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
01
Year of publication
2001
Pages
89 - 90
Database
ISI
SICI code
1359-7345(2001):01<89:SSO['W>2.0.ZU;2-3
Abstract
Two decanuclear cyclic Cr(iii) complexes have been synthesised in high yiel d by solvothermal techniques: magnetic susceptibility studies reveal ferrom agnetic Cr . . . Cr exchange in one, and antiferromagnetic Cr . . . Cr exch ange in the other.