A. Kishida et al., Remarkable effect of manganese center on catalytic activity for decomposition of hydrogen peroxide, CHEM LETT, (12), 2000, pp. 1374-1375
The structures of manganese centers remarkably influenced the catalytic act
ivities for the decomposition of hydrogen peroxide and tri-manganese-substi
tuted silicotungstate, [alpha -SiW9{Mn-III(H2O)}(3)O-37](7-) was the most a
ctive among the polyoxometalates tested and other inorganic manganese compo
unds.