Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

Authors
Kwon, E Sakamoto, K Kabuto, C Kira, M
Citation
E. Kwon et al., Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles, CHEM LETT, (12), 2000, pp. 1416-1417
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
12
Year of publication
2000
Pages
1416 - 1417
Database
ISI
SICI code
0366-7022(200012):12<1416:HOSAUD>2.0.ZU;2-C
Abstract
The hydrogenation of bistrimethylsilylactylene, bis(trimethylsilyl)-1,3-diy nes, and related silylalkynes giving the corresponding saturated compounds were achieved by using diimide prepared in situ from p-toluenesulfonyl hydr azide in diglyme. The present method was applicable to the synthesis of sat urated 12- and 18-membered oligosilacycloalkanes.