The present paper reports an experimental analysis carried on turbulent jet
flames with the aim of contributing to improving the knowledge on counterg
radient diffusion of a scalar in nonpremixed flames. The experimental progr
am includes the characterization of mean and fluctuating velocity and tempe
rature fields, as well as the correlation between velocity and temperature
fluctuations. The results quantify that velocity-temperature correlation te
nds to exhibit zones of nongradient turbulent heat transfer. Conditional sa
mpling and averaging is employed to investigate the statistical characteris
tics of turbulent transport processes of the scalar. In addition, the condi
tional analysis reported herein demonstrates that countergradient contribut
ion remains strong even in those regions of the flow where velocity-tempera
ture correlations are in the gradient sense. A further analysis shows that
this result can be extended to characterize mixture fraction flux within th
e region analyzed, and highlights the necessity that prediction of such qua
ntities must be based on a second moment model closure rather than on an ef
fective viscosity. (C) 2001 by The Combustion Institute.