On the possible determinants of asymmetric induction in dihydronaphthaleneepoxidation catalyzed by manganese chiroporphyrins. Solution and solid-state probes of non-planar porphyrin distortion

Authors
Pecaut, J Perollier, C Ramasseul, R Marchon, JC
Citation
J. Pecaut et al., On the possible determinants of asymmetric induction in dihydronaphthaleneepoxidation catalyzed by manganese chiroporphyrins. Solution and solid-state probes of non-planar porphyrin distortion, CR AC S IIC, 3(9), 2000, pp. 743-746
Citations number
11
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609 → ACNP
Volume
3
Issue
9
Year of publication
2000
Pages
743 - 746
Database
ISI
SICI code
1387-1609(200009)3:9<743:OTPDOA>2.0.ZU;2-2
Abstract
Asymmetric induction in the title reaction is highly correlated to the porp hyrin distortion in solution probed by NMR, bur it is poorly correlated to the solid-state distortion observed by X-ray crystallography. (C) 2000 Acad emie des sciences/Editions scientifiques et medicales: Elsevier SAS.