Introductory Lecture - Excited states at surfaces: Fano profiles in STM spectroscopy of adsorbates

Citation
Jw. Gadzuk et M. Plihal, Introductory Lecture - Excited states at surfaces: Fano profiles in STM spectroscopy of adsorbates, FARADAY DIS, (117), 2000, pp. 1-13
Citations number
68
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
FARADAY DISCUSSIONS
ISSN journal
13596640 → ACNP
Issue
117
Year of publication
2000
Pages
1 - 13
Database
ISI
SICI code
1359-6640(2000):117<1:IL-ESA>2.0.ZU;2-0
Abstract
The Fano-Anderson model for a discrete state embedded within a continuum is revisited within the context of excitation and decay processes which lead to some manifestations of Fano lineshape profiles. The phenomenon of resona nce tunneling between an STM tip and a metal surface upon which there are i solated adsorbed atoms is discussed and the relationship between the spectr oscopic signature of such systems and that of the Fano profile is taken up. Recent experimental studies of Kondo systems of magnetic adsorbates such a s Co and Ce adsorbed on noble metal (111) surfaces have motivated this work .