Synthesis and dehydrative condensation of monomeric hydroxoruthenium complexes with hydrotris(3,5-diisopropylpyrazolyl)borate ligand, Tp(2)(iPr)Ru(L-2)-OH (L-2 = dppe, bipy)

Authors
Akita, M Takahashi, Y Hikichi, S Moro-oka, Y
Citation
M. Akita et al., Synthesis and dehydrative condensation of monomeric hydroxoruthenium complexes with hydrotris(3,5-diisopropylpyrazolyl)borate ligand, Tp(2)(iPr)Ru(L-2)-OH (L-2 = dppe, bipy), INORG CHEM, 40(1), 2001, pp. 169
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
1
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010101)40:1<169:SADCOM>2.0.ZU;2-0
Abstract
Monomeric neutral hydroxoruthenium complexes, Tp(2)(iPr)RuOH(L-2) (L-2 = dp pe, bipy), are prepared by deprotonation of aquo complexes, and it is confi rmed that dehydrative condensation reaction of the hydroxo complexes with c arboxylic acids involves protonation of hydroxo ligand followed by replacem ent of the resultant aquo ligand by the nucleophile.