A (NdCuII)-Cu-III molecular material with a honeycomb-like structure

Authors
Daiguebonne, C Guillou, O Kahn, ML Kahn, O Oushoorn, RL Boubekeur, K
Citation
C. Daiguebonne et al., A (NdCuII)-Cu-III molecular material with a honeycomb-like structure, INORG CHEM, 40(1), 2001, pp. 176
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
1
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010101)40:1<176:A(MMWA>2.0.ZU;2-3
Abstract
The first two-dimensional molecular material Nd(III)-Cu(II) has been synthe sized by reaction in DMF of [Cu(opba)](2-) and Nd3+. The compound {Nd-2[Cu( opba)(0.5)(ox)](3). 9DMF}.4.5DMF has been structurally characterized. Its c rystalline structure can be described as the superposition of honeycomb-lik e molecular motifs. This material exhibits a quasi nonmagnetic ground state at low temperature.