Synthesis and characterization of the diruthenium(III) complexes Ru-2(F(4)Oap)(2)(F(5)ap)(2) and Ru-2(F(4)Oap)(F(4)NCNap)(F(5)ap)(2) where F(4)Oap isthe 2-(3,4,5,6-tetrafluoro-2-oxoanilino)pyridinate anion, F(4)NCNap is the2-(3,4,5,6-tetrafluoro-2-cyanamidoanilino)pyridinate anion, and F(5)ap is the 2-(2,3,4,5,6-pentafluoroanilino)pyridinate anion

Authors
Bear, JL Li, YL Han, BC Van Caemelbecke, E Kadish, KM
Citation
Jl. Bear et al., Synthesis and characterization of the diruthenium(III) complexes Ru-2(F(4)Oap)(2)(F(5)ap)(2) and Ru-2(F(4)Oap)(F(4)NCNap)(F(5)ap)(2) where F(4)Oap isthe 2-(3,4,5,6-tetrafluoro-2-oxoanilino)pyridinate anion, F(4)NCNap is the2-(3,4,5,6-tetrafluoro-2-cyanamidoanilino)pyridinate anion, and F(5)ap is the 2-(2,3,4,5,6-pentafluoroanilino)pyridinate anion, INORG CHEM, 40(1), 2001, pp. 182
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
1
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010101)40:1<182:SACOTD>2.0.ZU;2-P
Abstract
Two diruthenium(III) complexes with mixed anionic bridging ligands are synt hesized and characterized as to their structural, electrochemical, and spec troscopic properties. Both compounds undergo not only metal-centered but al so ligand-centered electrode reactions and this is accounted for by their q uinone-type structures.