{TpRe(bpy)}: A novel pentaaminerhenium system that stabilizes both high and low oxidation states (Tp = hydridotris(pyrazolyl)borate; bpy 2,2 '-bipyridyl)

Authors
Gunnoe, TB Meiere, SH Sabat, M Harman, WD
Citation
Tb. Gunnoe et al., {TpRe(bpy)}: A novel pentaaminerhenium system that stabilizes both high and low oxidation states (Tp = hydridotris(pyrazolyl)borate; bpy 2,2 '-bipyridyl), INORG CHEM, 39(26), 2000, pp. 6127
Citations number
49
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
26
Year of publication
2000
Database
ISI
SICI code
0020-1669(200012)39:26<6127:{ANPST>2.0.ZU;2-#
Abstract
The complexes [TpRe(bpy)(CI)]OTf and TpRe(bpy)-(eta (2)-cyclopentene) can b e prepared from TpRe(Cl-2)(O= PMe3). The stability of rhenium in both low a nd high oxidation states is attributed to the flexible electronic nature of the polypyridyl and pyrazolyl ligands.