Dendrimer-bound tertiary phosphines for alkene hydroformylation

Citation
L. Ropartz et al., Dendrimer-bound tertiary phosphines for alkene hydroformylation, INORG CH C, 3(12), 2000, pp. 714-717
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
12
Year of publication
2000
Pages
714 - 717
Database
ISI
SICI code
1387-7003(200012)3:12<714:DTPFAH>2.0.ZU;2-S
Abstract
Dendrimer-based phosphines with 8, 24 and 72 PR2 arms (R = Me, Et. hexyl, C y or Ph) based on polyhedral oligomeric silsesquioxane (POSS) cores have be en synthesized and shown to catalyse hydroformylation reactions, in some ca ses with higher linear:branched product ratio (1:b) than their monomeric an alogues. (C) 2000 Elsevier Science S.A. All rights reserved.