Synthesis and crystal structure of the double polyphosphate CsMn(PO3)(4)

Authors
Murashova, EV Chudinova, NN
Citation
Ev. Murashova et Nn. Chudinova, Synthesis and crystal structure of the double polyphosphate CsMn(PO3)(4), INORG MATER, 36(12), 2000, pp. 1277-1281
Citations number
15
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INORGANIC MATERIALS
ISSN journal
00201685 → ACNP
Volume
36
Issue
12
Year of publication
2000
Pages
1277 - 1281
Database
ISI
SICI code
0020-1685(200012)36:12<1277:SACSOT>2.0.ZU;2-R
Abstract
The double polyphosphate CsMn(PO3)(4) was prepared by crystallization from molten polyphosphoric acids containing cesium and manganese cations, and it s crystal structure was determined: monoclinic cell, sp. gr. P2(1), Z = 2, a = 5.212 Angstrom, b = 13.581 Angstrom, c = 7.394 Angstrom, beta = 102.11 degrees. This compound has no structural analogs.