We report x-ray, EXAFS and neutron diffraction experiments on stress-r
elieved (SR) and field-annealed (FA) ribbons of Fe78Si9B13 using optim
ized geometries to measure the structural and magnetic anisotropy to u
nprecedented accuracy. A peak of magnitude similar to 5% of the main p
eak height is found in the Delta S(Q) pattern from three independent n
eutron experiments on the FA ribbons, at Q similar to 3 Angstrom(-1).
We establish that this peak is of magnetic origin, arising from moment
s that to some extent lie perpendicularly to the anneal field directio
n, and is associated with local structure. We show that this anistropy
is consistent with a recently proposed disturbed exchange model, sugg
esting that the result represents the first direct observation of the
existence of antiferromagnetically coupled moments within an amorphous
ferromagnetic alloy.