The generation of traps in SiOx/ZrO2 and SiOx/TiO2 gate dielectric stacks d
uring gate voltage stress of metal-oxide-semiconductor capacitors is invest
igated. The voltage and temperature dependence of the trap generation rate
is extracted from the analysis of the gate current increase observed during
the electrical stress. These data can be explained by a model based on a t
wo-stage degradation process, i.e., (1) H+ proton generation in the high pe
rmittivity gate dielectric layer by the injected electrons and (2) transpor
t of the H+ protons in the high permittivity material, resulting in bond br
eaking and trap generation. The threshold electron energy for H+ generation
and the activation energy for H+ transport and bond breaking are extracted
from fits to the experimental results. (C) 2001 American Institute of Phys
ics.