SYNTHESIS AND STRUCTURAL INVESTIGATION OF SOME CYCLIC KETENE ACETALS,DETECTION OF AN UNEXPECTED PROTON-TRANSFER IN (3-BENZYLTHIAZOLIDIN-2-YLIDENE)ACETAMIDE
C. Szantay et al., SYNTHESIS AND STRUCTURAL INVESTIGATION OF SOME CYCLIC KETENE ACETALS,DETECTION OF AN UNEXPECTED PROTON-TRANSFER IN (3-BENZYLTHIAZOLIDIN-2-YLIDENE)ACETAMIDE, Heterocycles, 45(6), 1997, pp. 1081-1095
The thiazolidines (2) and (3) were synthesized. Some of these compound
s exhibit unexpected chemical behavior; e.g in the case of (3-benzylth
iazolidin-2-ylidene)acetamide (3b), NMR investigations revealed the pr
esence of chemical exchange involving C(6)-H and the NH2 protons.