M. Garciavalles et al., COLORED MINERAL COATINGS ON MONUMENT SURFACES AS A RESULT OF BIOMINERALIZATION - THE CASE OF THE TARRAGONA CATHEDRAL (CATALONIA), Applied geochemistry, 12(3), 1997, pp. 255-266
Successive coloured coatings on the Taragona cathedral (Catalonia) wer
e analyzed using chemical, microbiological and mineralogical technique
s. The coatings consist of mainly biogenic minerals (calcite, several
oxalates, phosphates) and their fabric and composition is independent
of the underlying rock. The origin of the crusts or patinas is attribu
ted to bygone (sub-fossil) microflores which formed biofilms and micro
bial mats on and within the surface of the limestones and marbles of t
he cathedral. The staining of the patina layers is not related to the
mineral colours, nor to anthropogenic dust or fly-ashes. The colours a
re most probably organic pigments embedded between the crystals and Fe
- and Mn-organic compounds remaining from bioactivity. A sequential hy
pothesis of the origin(s) of the patina layers is given. (C) 1997 Else
vier Science Ltd.