Synthesis, characterization, and polymerization of bismaleimides containing ester groups in the backbone and chlorine atoms

Citation
M. Sava et al., Synthesis, characterization, and polymerization of bismaleimides containing ester groups in the backbone and chlorine atoms, J MACR S PU, 37(12), 2000, pp. 1587-1599
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
ISSN journal
10601325 → ACNP
Volume
37
Issue
12
Year of publication
2000
Pages
1587 - 1599
Database
ISI
SICI code
1060-1325(2000)37:12<1587:SCAPOB>2.0.ZU;2-S
Abstract
New chlorinated bismaleimides with ester units were synthesized by the reac tion of 3(4)-maleimido benzoic acid chloride [3(4)-MBAC] with 2,2-bis(3,5-d ichloro-4-hydroxy-phenyl)-pro-pan and 2,2-bis(3,5-dichloro-4-ethanol phenox y)propan using chloroform as solvent and triethylamine (TEA) as acid accept or. The bismaleimides were polymerized with 1,2-bis [2-(4-aminophenoxy)etho xy]ethane (BAPEE). The relationship between the structure and the propertie s of the obtained bismaleimides and reaction conditions for the synthesis o f resin were studied. The properties of these monomers and polymers were co mpared with those of monomer and polymer derived from bisphenol A.