The CMR manganites Ln(1 - x)A(x)MnO(3) with the perovskite structure form a
very important family of magnetic oxides, studied for their fascinating co
lossal magnetotransport properties. In this review, we discuss two phenomen
a, charge ordering and phase separation, which are crucial for the appearan
ce of CMR in these oxides. We propose a new route to CMR, based on the Mn-s
ite doping of these materials by other cations, such as Cr, Co, Ni and Ru.