Dielectric ceramic materials have been studied for decades due to both thei
r application in important technologies and the fundamentally interesting r
elationships among their crystal chemistry, crystal structures, and physica
l properties. Recent dramatic changes in microelectronics and in particular
wireless communications technologies have made the importance of materials
with the unusual combination of high dielectric constant, low dielectric l
oss and low temperature dependence of dielectric constant of great interest
. In this review, the present state of knowledge of the chemistry, structur
e, and dielectric properties of these materials, as well as examples of our
own work, are described.