The reduction of nitrobenzene as catalyzed by poly(4-vinylpyridine)-immobilized [Rh(COD)(amine)(2)](PF6) complexes under WGSR conditions

Catalysts for the selective reduction of nitrobenzene to aniline prepared f rom poly(4-vinylpyridine) (P(4-VP))-immobilized [Rh(COD)(amine)(2)](PF6)(CO D=1,5-cyclooctadiene, amine =4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) complexes in contact with 80% aqueous 2-ethox yethanol, 1x10(-4) mol Rh/0.5 g of polymer, 0.9 atm of CO pressure at 100 d egreesC under water-gas shift reaction conditions (WGSR, CO+H2O CO2+H-2) ar e described. Aniline production (milimole/3 h) depends on the nature of the amine and decreases in the following order: 2-picoline (0.65)>4-picoline ( 0.59)greater than or equal to 3-picoline (0.56)>pyridine (0.49)>3,5-lutidin e (0.38)>2,6-lutidine (0.34). The immobilized [Rh(COD)(2-picoline)21 (PF6) complex was found to be reusable as a catalyst for the title reaction. The Rh/2-picoline complex was immobilized to the pyridine groups of the organic polymer as supported by Fourier transform infrared (FT-IR), electron param agnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS), UV/Vis/dif fuse reflectance (DR) spectroscopies, and scanning electron microscopy (SEM ) studies. (C) 2000 Elsevier Science B.V. All rights reserved.